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The Binding Energies of
Integral Alpha Particle Nuclides

The binding energy of the He4 nucleus, the alpha particle, is relatively high compared to that of close by nuclides. It is 28.3 million electron volts (MeV) compared with 2.2 MeV for the H2, deuteron, 7.7 MeV for the He3 and 8.5 MeV for the H3, tritium, nuclides. On the other hand for nuclides which include the components of the alpha particle plus additional nucleons the binding energies at the 28 MeV level. This suggest that when the components of an alpha particle are present, two protons and two neutrons, such a particle is formed.

When the binding energies of nuclides which could contain an integral number of alpha particles are reviewed, as in the table below, one finds that there is generally an excess in binding energy above that which could be attributed to the formation of alpha particles.

The Binding Energies of Nuclei Which Could
Contain an Integral Number of Alpha Particles
Element Neutrons Protons Binding
Energy
Number of
Alpha Particles
Binding
Energy
Difference
He 2 2 28.295674 1 28.295674 0
Be 4 4 56.49951 2 56.591348 0.091838
C 6 6 92.161728 3 84.887022 7.274706
O 8 8 127.619336 4 113.182696 14.43664
Ne 10 10 160.644859 5 141.47837 19.166489
Mg 12 12 198.25689 6 169.774044 28.482846
Si 14 14 236.53689 7 198.069718 38.467172
S 16 16 271.78066 8 226.365392 45.415268
Ar 18 18 306.7157 9 254.661066 52.054634
Ca 20 20 342.052 10 282.95674 59.09526
Ti 22 22 375.4747 11 311.2524 64.22229
Cr 24 24 411.462 12 339.548088 71.913912
Fe 26 26 447.697 13 367.843762 79.853238
Ni 28 28 483.988 14 396.139436 87.848564
Zn 30 30 514.992 15 424.43511 90.55689
Ge 32 32 545.95 16 452.730784 93.219216
Se 34 34 576.4 17 481.026458 95.373542
Kr 36 36 607.1 18 509.322132 97.777868
Sr 38 38 638.1 19 537.617806 100.482194
Zr 40 40 669.8 20 565.91348 103.88652
Mo 42 42 700.9 21 594.209154 106.690846
Ru 44 44 731.4 22 622.504828 108.895172
Pd 46 46 762.1 23 650.800502 111.299498
Cd 48 48 793.4 24 679.096176 114.303824
Sn 50 50 824.9 25 707.39185 117.50815

The graph of the excess binding energy shown as the last column in the above table displays some interesting characteristics.

There is no significant excess binding energy for two alpha particles but for three there is. The additional binding energy for the number of alpha particles above two is roughly constant at about 7 MeV per additional alpha particle until a level of 14 alpha particles is reached. Thereafter the increase is about 3 MeV per additional alpha particle, as shown below.

This suggests that the equation which would fit the data for the binding energies of the integral alpha particle nuclides is of the form

BE = c1#α + c2u(#α-2) + c3u(#α-14)

where #α is the number of alpha particles and u(z) is the ramp function such that if z<0 then u(z)=0 and otherwise u(z)=z. The coefficients c1 and c2 are positive and c3 negative.

A multiple regression of the binding energies of the integral alpha particle binding energies on functions of the number of alpha particles yields

BE = 29.25983#α + 5.83034u(#α-2) −4.76477u(#α-14)
[22.3]      [4.2]     [-15.3]
R² = 0.999917

The figures in square brackets below the coefficients are the t-ratios for the coefficients, the ratio of the coefficient to its standard deviation. The statistical fit is quite good.

The value of 29.25983 MeV for the effect of an alpha particle on binding energy instead of 28.29567 MeV, the binding energy of a single alpha particle, could be construed to be evidence that the 28.29567 MeV is an underestimate. Such an underestimate could come as result of the mass of a neutron being underestimated by 0.48 MeV, about one electron rest mass energy.

(To be continued.)


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