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Maria Goeppert Mayer and Hans Jensen examining the properties of the isotopes of elements discerned that isotopes in which the proton and/or the neutron numbers were particular values have notable properties such as stability. These magic numbers are
Magic Numbers | 2 | 8 | 20 | 28 | 50 | 82 | 126 |
The difference in consecutive magic numbers represent the maximum occupancy of a shell. There is no obvious rule for establishing the maximum occupancy for proton shells as there is for electron shells. Furthermore Mayer and Jensen relied primarily on the number of stable isotopes for a number compared to the number for adjacent proton numbers.
The table below shows the relationship between the number of stable isotopes and the atomic (proton) number.
Proton Number | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 |
Number of Stable Isotopes |
2 | 2 | 2 | 1 | 2 | 2 | 2 | 3 | 1 | 3 |
Proton Number | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | 20 |
Number of Stable Isotopes |
1 | 3 | 1 | 3 | 1 | 4 | 2 | 3 | 2 | 5 |
Proton Number | 21 | 22 | 23 | 24 | 25 | 26 | 27 | 28 | 29 | 30 |
Number of Stable Isotopes |
1 | 5 | 1 | 3 | 1 | 4 | 1 | 5 | 2 | 5 |
Proton Number | 31 | 32 | 33 | 34 | 35 | 36 | 37 | 38 | 39 | 40 |
Number of Stable Isotopes |
2 | 4 | 1 | 5 | 2 | 5 | 1 | 4 | 1 | 4 |
Proton Number | 41 | 42 | 43 | 44 | 45 | 46 | 47 | 48 | 49 | 50 |
Number of Stable Isotopes |
1 | 6 | 0 | 7 | 1 | 6 | 2 | 6 | 1 | 10 |
Proton Number | 51 | 52 | 53 | 54 | 55 | 56 | 57 | 58 | 59 | 60 |
Number of Stable Isotopes |
2 | 4 | 1 | 9 | 1 | 6 | 1 | 2 | 1 | 5 |
Proton Number | 61 | 62 | 63 | 64 | 65 | 66 | 67 | 68 | 69 | 70 |
Number of Stable Isotopes |
0 | 4 | 1 | 6 | 1 | 7 | 1 | 6 | 1 | 7 |
Proton Number | 71 | 72 | 73 | 74 | 75 | 76 | 77 | 78 | 79 | 80 |
Number of Stable Isotopes |
1 | 5 | 2 | 4 | 1 | 5 | 2 | 5 | 1 | 6 |
Proton Number | 81 | 82 | 83 | 84 | 85 | 86 | 87 | 88 | 89 | 90 |
Number of Stable Isotopes |
2 | 3 |
The odd-even alternation indicates a pairing of protons within the nucleus; perhaps the existence of alpha particle subsystems. It is not clear why some numbers were designated magic and other not. The average number of stable isotopes increases with proton number reaching a peak of 10 for proton number 50 (Tin) and declines generally thereafter. But there are 9 stable isotopes for proton number 54, Xenon. Apparently 54 was excluded because it is too close to 50 and thus would imply a proton shell of maximum occupancy 4.
There is another way to establishing the occupancy of a filled shell. Their incremental binding energy of an additional proton falls once a proton shelll is filled and the additional proton has to go into a higher shell. This test confirms the Mayer-Jensen magic numbers but it identifies 6 and 14 as magic numbers. The significance of this is that if 6 and 14 are included in the series and 8 and 20 left out there is a simple algorithm for generating the magic number. However there is no question but 8 and 20 are special. Their specialness can be interpreted in terms of the filling of proton subshells. The first two proton shells have occupancies of 2 and 4, respectively. thus the seventh and eighth protons go into the third proton shell and fill a subshell of occupancy 2. The ninth through fourteenth protons then fill out the rest of the third shell. Proton number 20 could represent the filling of two subshells in the fourth proton shell. The striking suggestion from the case of 8 and 20 is that the occupancy numbers for the subshells are the same as those for the lower shells. This proposition is tested in the following table.
The Number of Stable Isotopes for various proposed subshells |
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Proton Subshell Numbers | ||||
Proton Shell Numbers | 2 | 6 | 14 | 28 |
2 | (2,1,2) | |||
6 | (2,3,1) | |||
14 | (1,4,2) | (2,5,1) | ||
28 | (2,5,2) | (1,5,2) | (1,6,0) | |
50 | (2,4,1) | (2,4,1) | (1,6,1) | (2,5,1) |
What is displayed in the table is the number of stable isotopes for a triplet of proton numbers in the j-th subshell after the i-th shell is fillled. For example, for the subshell of 2 in the fourth shell after the first three shells are filled with 14 protons. The middle number in the triplet (1, 4, 2) is the number of stable isotopes for proton number 16=14+2. The numbers on either side are the stable isotopes for proton numbers 15 and 17. In all but one case the middle number is impressively larger than the numbers on either side. The case of proton number 54 suggests that the can be more than one subshell of a certain size.
The real test of the magic-ness of a subshell number is whether it also appears so in terms of the neutron number. The number of stable isotopes as a function of neutron number are:
Neutron Number | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 |
Number of Stable Isotopes |
2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 3 |
Neutron Number | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | 20 |
Number of Stable Isotopes |
1 | 3 | 1 | 3 | 1 | 3 | 1 | 3 | 0 | 5 |
Neutron Number | 21 | 22 | 23 | 24 | 25 | 26 | 27 | 28 | 29 | 30 |
Number of Stable Isotopes |
0 | 3 | 2 | 3 | 1 | 4 | 4 | 4 | 1 | 4 |
Neutron Number | 31 | 32 | 33 | 34 | 35 | 36 | 37 | 38 | 39 | 40 |
Number of Stable Isotopes |
1 | 3 | 1 | 3 | 0 | 2 | 3 | 7 | 1 | 4 |
Neutron Number | 41 | 42 | 43 | 44 | 45 | 46 | 47 | 48 | 49 | 50 |
Number of Stable Isotopes |
1 | 5 | 3 | 4 | 1 | 3 | 1 | 4 | 2 | 5 |
Neutron Number | 51 | 52 | 53 | 54 | 55 | 56 | 57 | 58 | 59 | 60 |
Number of Stable Isotopes |
2 | 4 | 3 | 4 | 2 | 3 | 2 | 3 | 1 | 3 |
Neutron Number | 61 | 62 | 63 | 64 | 65 | 66 | 67 | 68 | 69 | 70 |
Number of Stable Isotopes |
1 | 5 | 1 | 3 | 1 | 3 | 2 | 2 | 1 | 7 |
Neutron Number | 71 | 72 | 73 | 74 | 75 | 76 | 77 | 78 | 79 | 80 |
Number of Stable Isotopes |
4 | 5 | 1 | 5 | 2 | 4 | 2 | 4 | 3 | 3 |
Neutron Number | 81 | 82 | 83 | 84 | 85 | 86 | 87 | 88 | 89 | 90 |
Number of Stable Isotopes |
2 | 8 | 4 | 1 | 3 | 1 | 2 | 4 | 0 | 6 |
Neutron Number | 91 | 92 | 93 | 94 | 95 | 96 | 97 | 98 | 99 | 100 |
Number of Stable Isotopes |
2 | 4 | 1 | 4 | 1 | 6 | 1 | 5 | 2 | 4 |
Neutron Number | 101 | 102 | 103 | 104 | 105 | 106 | 107 | 108 | 109 | 110 |
Number of Stable Isotopes |
2 | 2 | 2 | 5 | 2 | 2 | 0 | 3 | 0 | 3 |
Neutron Number | 111 | 112 | 113 | 114 | 115 | 116 | 117 | 118 | 119 | 120 |
Number of Stable Isotopes |
2 | 2 | 1 | 2 | 1 | 2 | 3 | 1 | 3 | 3 |
Neutron Number | 121 | 122 | 123 | 124 | 125 | 126 | 127 | 128 | 129 | 130 |
Number of Stable Isotopes |
1 | 3 | 1 | 3 | 0 | 1 | 1 | 0 | 0 | 3 |
Neutron Number | 131 | 132 | 133 | 134 | 135 | 136 | 137 | 138 | 139 | 140 |
Number of Stable Isotopes |
0 | 0 | 0 | 0 | 0 | 3 | 1 | 1 | 1 | 0 |
The Number of Stable Isotones for various proposed neutron subshells |
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Neutron Subshell Numbers | |||||
Neutron Shell Numbers | 2 | 6 | 14 | 28 | 50 |
2 | (1,1,2) | ||||
6 | (2,2,1) | ||||
14 | (1,3,1) | (0,5,0) | |||
28 | (1,3,1) | (1,3,0) | (1,5,3) | ||
50 | (2,4,3) | (2,3,2) | (1,3,1) | (2,4,3) | |
82 | (4,1,3) | (2,4,0) | (1,6,1) | (0,3,2) | (0,0,0) |
126 | (1,0,0) | (0,0,0) | (1,0,0) |
Generally the results confirm the expectation that the middle number is notably larger than the numbers on either side.
(To be continued.)
For more on nuclear subshells see Subshells.
For more on the nuclear shell model see Nuclear Shell Structure
For a simple explanation of the nuclear magic numbers see Algorithm for magic numbers.
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